Process to make allyl chloride and reactor useful in that process

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United States of America Patent

PATENT NO 5504266
SERIAL NO

08449635

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ATTORNEY / AGENT: (SPONSORED)

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Abstract

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Allyl halide is produced in high yields and purity with minimal carbon formation using a process of: (1) initially reacting propylene and molecular halogen in a molar ratio of at least about 2.5:1 in a 'continuously stirred tank reactor' (CSTR) zone under conditions suitable to provide a reaction temperature of about 400.degree. C. to 525.degree. C. to partially convert propylene and chlorine into allyl chloride; and (2) feeding an effluent from Step (1) into a plug-flow reactor zone where the reaction is continued at a temperature of about 400.degree. C. to 525.degree. C. until essentially all of the chlorine is consumed. A preferred reactor for the process contains: (1) a spherical, egg-shaped or oval reactor zone; (2) a tubular reactor zone attached to the spherical, egg-shaped or oval reactor zone; (3) one or more inlets for injecting gaseous reagents into the spherical, oval or egg-shaped reactor zone; and (4) one or more outlets from the tubular reactor zone for withdrawing a gaseous product.

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Patent Owner(s)

  • BLUE CUBE IP LLC

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Baker, John F Freeport, TX 10 176
Beckett, Paul C Lake Jackson, TX 2 28
Tirtowidjojo, Max M Lake Jackson, TX 32 412

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