SiOCH low k surface protection layer formation by CxHy gas plasma treatment

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United States of America Patent

PATENT NO 6962869
SERIAL NO

10270974

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ATTORNEY / AGENT: (SPONSORED)

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Abstract

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A method of protecting a low k dielectric layer that is preferably comprised of a material containing Si, O, C, and H is described. The dielectric layer is subjected to a gas plasma that is generated from a CXHY gas which is preferably ethylene. Optionally, hydrogen may be added to the CXHY gas. Another alternative is a two step plasma process involving a first plasma treatment of CXHY or CXHY combined with H2 and a second plasma treatment with H2. The modified dielectric layer provides improved adhesion to anti-reflective layers and to a barrier metal layer in a damascene process. The modified dielectric layer also has a low CMP rate that prevents scratch defects and an oxide recess from occurring next to the metal layer on the surface of the damascene stack. The plasma treatments are preferably done in the same chamber in which the dielectric layer is deposited.

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Patent Owner(s)

  • TAIWAN SEMICONDUCTOR MANUFACTURING COMPANY, LTD.

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Bao, Tien-I Hsin-chu, TW 276 4659
Jang, Syun-Ming Hsin-chu, TW 374 6646
Ko, Chung-Chi Tainan, TW 123 1188
Li, Lih-Ping Hsinchu, TW 24 262
Lu, Hsin-Hsien Hsin chu, TW 34 254
Song, Aaron Hsin-Chu, TW 2 127

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