Compounds and methods for generating oxygen and free radicals used in general oxidation and reduction reactions
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United States of America Patent
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Nov 21, 1995
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app pub date -
Jan 4, 1995
filing date -
Jan 5, 1993
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Abstract
Composition and methods; for carrying out a variety of oxidation reactions, reduction reactions, or both utilizing a free radical generating catalyst, a mediator, and a reductant are disclosed. The free radical generating catalyst is generally a peroxidase obtained from living organisms, such as white rot fungi. Suitable peroxidases include lignin peroxidase, horse radish peroxidase, and lactoperoxidase. Suitable mediators include veratryl alcohol, iodine, methoxybenzenes, Mn II, and ABTS. Suitable reductants include EDTA, oxalate, hydroquinones, quinones plus quinone reductase, and hydrogen peroxide.
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