Process for the production of polyphenylene oxides
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United States of America Patent
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Aug 27, 1985
Grant Date -
N/A
app pub date -
Feb 23, 1984
filing date -
Apr 16, 1983
priority date (Note) -
Expired
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Abstract
A process for the production of polyphenylene oxides by the oxidative coupling of a diorthosubstituted phenol of the formula: ##STR1## wherein R and R' are an n-alkyl radical with 1 to about 6 carbon atoms or a phenyl radical in the presence of an oxidizing gas and an activated copper(II)-amine catalyst made of copper(II) salts, secondary aliphatic or cyclic amines having about 4 to 10 carbon atoms, and hydrobromides of the same or different secondary aliphatic or cyclic amines having about 4 to 10 carbon atoms, in a solvent mixture of a C.sub.6 -C.sub.8 aromatic hydrocarbon and a C.sub.1 -C.sub.4 aliphatic alcohol.
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