Compositionally and structurally disordered multiphase nickel hydroxide positive electrode for alkaline rechargeable electrochemical cells

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United States of America Patent

PATENT NO 5637423
SERIAL NO

08232782

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Abstract

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A positive electrode for use in alkaline rechargeable electrochemical cells comprising: a material comprising a compositionally and structurally disordered multiphase nickel hydroxide host matrix which includes at least one modifier. A process for forming a high loading uniformly distributed multiphase substantially nitrate free sintered positive electrode for use in an alkaline rechargeable electrochemical cell, the process comprising: (1) fabricating sintered electrode material by forming a slurry of nickel powder, water, carboxy methyl cellulose binder, methyl cellulose binder, and a poly(ethylene oxide) polymer; spreading the slurry on a preoxidized perforated nickel substrate; drying the slurry; and sintering the slurry; (2) impregnating the sintered electrode material using multiple impregnation cycles to attain high loading; and (3) forming the impregnated sinter into positive electrode material by presoaking the impregnated sinter in NaOH presoak tanks to substantially eliminate nitrates; brushing the presoaked impregnated sinter in a surface brushing station; charging the brushed impregnated sinter; discharging the charged impregnated sinter; rinsing the discharged impregnated sinter; and drying the rinsed impregnated sinter to complete the formation of positive electrode material.

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Patent Owner(s)

Patent OwnerAddress
CHEVRONTEXACO TECHNOLOGY VENTURES LLC3901 BRIARPARK HOUSTON TX 77042-5301

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Inventor(s)

Inventor Name Address # of filed Patents Total Citations
Fetcenko, Michael A Rochester Hills, MI 90 1133
Holland, Arthur Troy, MI 17 403
Ovshinsky, Stanford R Bloomfield Hills, MI 371 21172
Venkatesan, Srinivasan Southfield, MI 96 1122

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